Increased Selectivity in Photolytic Activation of Nanoassemblies Compared to Thermal Activation in On-Surface Ullmann Coupling

On-surface synthesis is a powerful method that has emerged recently to fabricate a large variety of atomically precise nanomaterials on surfaces based on polymerization. It is very successful for thermally activated reactions within the framework of heterogeneous catalysis. As a result, it often lacks selectivity. We propose to use selective activation of specific bonds as … Read more

Breaking Continuously Packed Bimetallic Sites to Singly Dispersed on Nonmetallic Support for Efficient Hydrogen Production

We have synthesized Pt1Zn3/ZnO, also termed 0.01 wt %Pt/ZnO-O2–H2, as a catalyst containing singly dispersed single-atom bimetallic sites, also called a catalyst of singly dispersed bimetallic sites or a catalyst of isolated single-atom bimetallic sites. Its catalytic activity in partial oxidation of methanol to hydrogen at 290 °C is found to be 2–3 orders of … Read more

Three Group Members Selected for Advanced School on Many-Body Physics

A clock tower framed by shadowed tree branches, captured in daylight against a clear sky.

Dr. Jia Shi, Bushra Ashraf, and Syeda Faiza Rubab Sherazi were selected to attend the School on Electron-Phonon Physics, Many-Body Perturbation Theory, and Computational Workflows. The school will be held June 10-16, 2024 at The University of Texas at Austin. The goal of this school is to introduce participants to first-principles calculations for electron-phonon physics … Read more

Anomalous isotope effect on the optical bandgap in a monolayer transition metal dichalcogenide semiconductor

Isotope effects have received increasing attention in materials science and engineering because altering isotopes directly affects phonons, which can affect both thermal properties and optoelectronic properties of conventional semiconductors. However, how isotopic mass affects the optoelectronic properties in 2D semiconductors remains unclear because of measurement uncertainties resulting from sample heterogeneities. Here, we report an anomalous … Read more

Mapping spin interactions from conductance peak splitting in Coulomb blockade

We investigate the transport properties of a quantum dot coupled to leads interacting with a multispin system using the generalized master equation within the Coulomb blockade regime. We find that if two states for each scattering region electron manifold are included, several signatures of the interacting spin system appear in steady-state transport properties. We provide a … Read more